Hot water has never been so important in our lives than in these six months. The pandemic has forced us to change our habits and one of those is to drink hot water. You must have seen water boiling and must have studied at school that water boils at 100 degrees Celsius. That’s true, or is it?
What if I told you that water can boil at 50 degrees Celsius? Or 400 degrees Celsius? Or -273 degrees Celsius (This temperature is called Absolute Zero. It is a point at which even atoms stop moving. Brrr!)? So, would you believe me? Any person who has learnt the concept of boiling point would call me wacky. So, here I am to challenge your knowledge.
Okay. Let us first define boiling point. What is it? School books usually define boiling point as “the temperature at which a liquid converts into a gas.” If we go according to this definition, then water definitely boils at 100 degrees Celsius. However, this definition is not acceptable in the big picture.
Before I get to the proper definition, let us study boiling according to the widely accepted definition. So, we say that at the temperature at which water forms bubbles, it is boiling. Even science has proven that if you keep a thermometer in boiling water (Don’t do that at home. It’s very dangerous!), it reads 100 degrees Celsius. So, this leads us to believe that water boils at 100 degrees.
Now, let us talk about two terms that we will use in our ‘new’ definition of boiling point namely vapour pressure and atmosphere pressure.
When a liquid boils, it converts to gas. No big deal there. Now, in the process, vapours are released. We know that the vapours are matter because they occupy space. And if it is matter, it should have some mass. And if it has some mass, it should exert some force (For example, we humans have some mass and we exert force on the Earth). So, the force exerted by a gas in a particular area is called vapour pressure (Pressure = Force/Area. So, force in a fixed amount of area is pressure. That’s why it is vapour pressure and not vapour force, because it only acts in a definite area, like on a container.
Next, we have atmospheric pressure. Let’s get to the point. It is the pressure the atmosphere (more specifically, the air above us) exerts on us. Simple enough? Now, we can move to the definition of boiling point.
Boiling point is defined as the temperature at which the vapour pressure of a liquid becomes equal to the atmospheric pressure. In simpler words, when the temperature provided to the liquid is enough for it to exert enough pressure to negate the atmospheric pressure (Atmospheric pressure is around 101000 Pa, meaning that 101000 units of force (Unit of force is Newtons) is acting on 1 square metre of surface. Pa stands for Pascal, which is the unit of pressure). Now, how can this logic be used to explain the “variable” boiling point of water?
Suppose you visit a hill station. If you have ever boiled water there, you might see that it boils relatively quicker. This is because the atmospheric pressure reduces at high altitudes. So, the vapour need not exert that much pressure to negate the atmospheric pressure and it boils at a lower temperature.
The same applies for water boiling at higher temperature. Just reduce your altitude and you’ll see the effect.
Finally, can water boil at absolute zero? Turns out, it can! Only problem is, absolute zero doesn’t exist naturally on Earth. But this can be observed in laboratories.
So, we see that if we alter the pressure, we can alter a liquid’s boiling point. Guess it’s just a game of pressure then, huh?
So, how was it? Did it get the water in your body boiling? Feel free to comment in the Comments section down below.
Author: Venkata Bhamidipati











